Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 17, Pages 5171-5174Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201501807
Keywords
alcohols; asymmetric catalysis; hydrogen transfer; iron; macrocyclic ligands
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Funding
- Swiss National Science Foundation [200020_146881]
- Swiss National Science Foundation (SNF) [200020_146881] Funding Source: Swiss National Science Foundation (SNF)
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Bis(isonitrile) iron(II) complexes bearing a C-2-symmetric diamino (NH)(2)P-2 macrocyclic ligand efficiently catalyze the hydrogenation of polar bonds of a broad scope of substrates (ketones, enones, and imines) in high yield (up to 99.5%), excellent enantioselectivity (up to 99% ee), and with low catalyst loading (generally 0.1 mol%). The catalyst can be easily tuned by modifying the substituents of the isonitrile ligand.
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