Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 12, Pages 3664-3668Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201410459
Keywords
aluminum fumarate; metal-organic frameworks; modeling; solid state NMR spectroscopy; X-ray diffraction
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Funding
- Global Frontier Center for Hybrid Interface Materials (GFHIM) [NRF-2013M3A6B1078879]
- Institut Universitaire de France
- KRICT through the Institutional Collaboration Research Program [KK-1407A46]
- National Research Foundation of Korea [2013M3A6B1078879] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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The synthesis of the commercially available aluminum fumarate sample A520 has been optimized and its structure analyzed through a combination of powder diffraction, solid-state NMR spectroscopy, molecular simulation, IR spectroscopy, and thermal analysis. A520 is an analogue of the MIL-53(Al)-BDC solid, but with a more rigid behavior. The differences between the commercial and the optimized samples in terms of defects have been investigated by in situ IR spectroscopy and correlated to their catalytic activity for ethanol dehydration.
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