Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 20, Pages 6024-6027Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201501048
Keywords
carbocyclization; chiral anion; chiral phosphoric acid; oxidation; palladium
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Funding
- European Research Council (ERC) [AdG 247014]
- Swedish Research Council [621-2013-4653]
- Berzelii Centre EXSELENT
- Knut and Alice Wallenberg Foundation
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An enantioselective oxidative carbocyclization-borylation of enallenes that is catalyzed by palladium(II) and a Bronsted acid was developed. Biphenol-type chiral phosphoric acids were superior co-catalysts for inducing the enantioselective cyclization. A number of chiral borylated carbocycles were synthesized in high enantiomeric excess.
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