4.5 Article

Preparation and characterization of ferric-impregnated granular ceramics (FGCs) for phosphorus removal from aqueous solution

Journal

CLEAN TECHNOLOGIES AND ENVIRONMENTAL POLICY
Volume 15, Issue 2, Pages 375-382

Publisher

SPRINGER
DOI: 10.1007/s10098-012-0527-9

Keywords

Ferric-impregnated granular ceramics (FGCs); Phosphorus adsorption; Adsorption isotherms; Adsorption kinetics

Funding

  1. Fundamental Research Funds for the Central Universities
  2. Water Pollution Control and Treatment Key Projects [2009ZX07 102-002-01]
  3. National Natural Science Foundation [31140082]

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In the present study, the ferric-impregnated granular ceramic (FGC) adsorbents were developed for the removal of phosphorus from aqueous solution. BET, SEM, and EDS were used to characterize the physical and chemical attributes (particle size, pore size and distribution, surface roughness, and chemical composition) of FGCs. Phosphorus adsorption characteristics were studied in a static batch system with respect to changes in contact time, initial phosphorus concentration, pH of solution, and temperature. The adsorption process was observed to follow a pseudo-first-order kinetic model, taking about 36 h to attain equilibrium. Phosphorus adsorption was found to be pH dependent and the maximum removal was obtained at pH 7.0-9.0. The experimental data denoted that the Langmuir isotherm model gave a more satisfactory fit for phosphorus removal than the Freundlich isotherm model. Results suggested that the novel adsorbent of FGCs had a good potential in remediation of phosphorus removal in aqueous solutions.

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