Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 20, Pages 6012-6015Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201500703
Keywords
asymmetric organocatalysis; carbamates; C-H functionalization; tetrahydropyridines; tetrahydro-beta-carbolines
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Funding
- National Science Foundation of China [21202093, 21472112, 21432003]
- Program for New Century Excellent Talents in University [NCET-13-0346]
- Shandong Science Fund for Distinguished Young Scholars [JQ201404]
- Young Scientist Foundation Grant of Shandong Province [BS2013YY001]
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The first organocatalytic enantioselective C-H alkenylation and arylation reactions of N-carbamoyl tetrahydropyridines and tetrahydro-beta-carbolines (THCs) are described. The metal-free processes represent an efficient and straightforward approach to a variety of structurally and electronically diverse a-substituted tetrahydropyridines and THCs in good yields with excellent regio- and enantioselectivities. Preliminary control experiments provide important insights into the reaction mechanism.
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