4.8 Article

Two-Dimensional Nanoporous Networks Formed by Liquid-to-Solid Transfer of Hydrogen-Bonded Macrocycles Built from DNA Bases

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 2, Pages 659-663

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201509233

Keywords

macrocycles; porous networks; self-assembly; supramolecular chemistry; surface assembly

Funding

  1. European Union (ERC) [279548]
  2. MICINN [CTQ2014-57729-P]
  3. Fund for Scientific Research-Flanders
  4. KU Leuven [GOA 11/003]
  5. Belgian Federal Science Policy Office [IAP-7/05]
  6. European Research Council, ERC [340324]
  7. European Research Council (ERC) [279548] Funding Source: European Research Council (ERC)

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We present an approach that makes use of DNA base pairing to produce hydrogen-bonded macrocycles whose supramolecular structure can be transferred from solution to a solid substrate. A hierarchical assembly process ultimately leads to two-dimensional nanostructured porous networks that are able to host size-complementary guests.

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