Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 22, Pages 6531-6535Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201501712
Keywords
asymmetric catalysis; hydrogen bonding; olefins; palladium; synthetic methods
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Funding
- Singapore Ministry of Education Academic Research Fund [MOE2013-T2-2-057, MOE2014-T1-001-021]
- Chinese Scholarship Council
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Asymmetric reductive Heck reaction of aryl halides is realized in high stereoselectivity. Hydrogen-bond donors, trialkylammonium salts in a glycol solvent, were used to promote halide dissociation from neutral arylpalladium complexes to access cationic, stereoselective pathways.
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