Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 26, Pages 7550-7554Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201501679
Keywords
alkynes; interlocked molecular cages; metathesis; supramolecular chemistry; thermodynamic control
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Funding
- National Science Foundation [DMR-1055705]
- Alfred P. Sloan Foundation
- Office of Energy Efficiency and Renewable Energy of the U.S. Department of Energy [DE-AC36-08GO28308]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1055705] Funding Source: National Science Foundation
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Highly stable permanently interlocked aryleneethynylene molecular cages were synthesized from simple triyne monomers using dynamic alkyne metathesis. The interlocked complexes are predominantly formed in the reaction solution in the absence of any recognition motif and were isolated in a pure form using column chromatography. This study is the first example of the thermodynamically controlled solution-phase synthesis of interlocked organic cages with high stability.
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