Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 52, Pages 15750-15755Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201508513
Keywords
bifunctional catalysts; biomass conversion; kinetics; lignin; ruthenium
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Funding
- Excellence Initiative of the German federal and state governments
- European Union (Marie Curie ITN SuBiCat) [PITN-GA-2013-607044]
- Deutscher Akademischer Austaush Dienst (DAAD)
- Alexander von Humboldt Foundation
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Ruthenium nanoparticles immobilized on acidfunctionalized supported ionic liquid phases (RuNPs@SILPs) act as efficient bifunctional catalysts in the hydrodeoxygenation of phenolic substrates under batch and continuous flow conditions. A synergistic interaction between the metal sites and acid groups within the bifunctional catalyst leads to enhanced catalytic activities for the overall transformation as compared to the individual steps catalyzed by the separate catalytic functionalities.
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