Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 33, Pages 9456-9466Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201504127
Keywords
asymmetric catalysis; desymmetrization; enantioselectivity; kinetic resolution; silylation
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Funding
- National Natural Science Foundation of China [21173064, 21472031]
- Fundamental Research Funds for the Central Universities [GK201501005]
- Zhejiang Provincial Natural Science Foundation of China [LR14B030001]
- National University of Singapore [R143-000-599-112]
- Singapore A*STAR SERC Public Sector Research Funding (PSF) [R-143-000-618-305]
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In recent years, remarkable progress has been made in the enantioselective silylation of alcohols. Owing to the successful site- and stereoselective functionalization of hydroxy groups, silyl ether formations have evolved from being a simple reaction for functional-group protection into a powerful enantioselective process. In this Minireview, we highlight important recent findings in this emerging field.
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