Journal
CHIRALITY
Volume 26, Issue 7, Pages 356-360Publisher
WILEY-BLACKWELL
DOI: 10.1002/chir.22297
Keywords
bromocyclization; bromophosphonium salt; N; N'-dimethylurea; 2-geranylphenol; phosphite; steric effect; urea
Funding
- JSPS, KAKENHI [23350039, 24245020]
- Program for Leading Graduate Schools Integrative Graduate Education and Research in Green Natural Sciences, MEXT, JAPAN
- Grants-in-Aid for Scientific Research [23350039, 11J05091] Funding Source: KAKEN
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Nucleophilic phosphite-urea cooperative catalysts are highly efficient for the bromonium-induced cyclization of 2-geranylphenols. Phosphite-N,N'-dimethylurea catalysts also show moderate activity, probably due to the steric effect of their bent conformation. Chirality 26:355-359, 2014. (c) 2014 Wiley Periodicals, Inc.
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