Journal
CHIRALITY
Volume 22, Issue 9, Pages 827-837Publisher
WILEY
DOI: 10.1002/chir.20843
Keywords
oxidative coupling; enantioselective synthesis; chiral ligand; BINOLs
Funding
- Scientific Research Foundation of the Education Ministry for Returned Chinese Scholars, Fudan University Youth Scientific Foundation
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The enantiomeric atropoisomers of 1,10-binaphthyl-2,20-diol (BINOL) have become one of the most widely used chiral ligands and auxiliaries for asymmetric synthesis. This review provides an overview of enantioselective synthesis of optical active BINOLs by straightforward asymmetric oxidative coupling of identical 2-naphthol and its substituted derivatives. Chirality 22:827-837, 2010. (C) 2010 Wiley-Liss, Inc.
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