Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 6, Pages 2205-2209Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201510027
Keywords
allylic compounds; boron; heterocycles; samarium iodide; synthetic methods
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Funding
- NIH [R01GM102403]
- Welch Foundation [I-1612]
- NSF [CHE030089]
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When activated by an acylating agent, pyridine boronic esters react with organometallic reagents to form a dihydropyridine boronic ester. This intermediate allows access to a number of valuable substituted pyridine, dihydropyridine, and piperidine products.
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