Journal
CHINESE JOURNAL OF POLYMER SCIENCE
Volume 31, Issue 3, Pages 434-443Publisher
SPRINGER
DOI: 10.1007/s10118-013-1229-4
Keywords
Nanocomposite-coated latex particles; PPy; Ag nanoparticles; Synthesis; Fluorescence quenching
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Funding
- National Natural Science Foundation of China [50673008, 50703002]
- Fundamental Research Funds for the Central Universities [JD1108]
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Submicron-sized Ag-polypyrrole/poly(styrene-co-methacrylic acid) (Ag-PPy/P(St-co-MAA)) composite particles were fabricated via a redox reaction between pyrrole and AgNO3 in the presence of P(St-co-MAA) soap-free latex. The products are characterized by transmission electron microscopy (TEM), electron diffraction spectra (EDS), Raman spectra, thermogravimetric analysis (TGA) and scanning electron microscopy (SEM). The results showed that Ag-PPy nanocomposites were in situ deposited onto the surface of P(St-co-MAA) latex particles tailored by carboxylic-acid groups. The nanocomposites of Ag-PPy distributed on the surface of polymer particles transformed from discretely dots to continuously coating as the reaction temperature increased from 15A degrees C to 60A degrees C. Strawberry-like composite particles were obtained at the reaction temperature of 60A degrees C. The TGA characterization confirmed that the Ag-PPy nanocomposites loading onto the P(St-co-MAA) particles were systematically controlled over a range of 6 wt%-42 wt% by changing the reaction temperatures. The fluorescence quenching effect of the Ag-PPy/P(St-co-MAA) composite particles was explored on Rhodamine B as a model molecule with the Stern-Volmer quenching constant K (SV) of 5.9 x 10(4) (g/mL)(-1). It is suggested that the fluorescence quenching effect is caused by the resonance energy transfer mechanism.
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