Journal
CHINESE JOURNAL OF POLYMER SCIENCE
Volume 27, Issue 2, Pages 195-208Publisher
SPRINGER
DOI: 10.1142/S0256767909003832
Keywords
Radical copolymerization; Copolymer microstructure; Copolymer composition; Monte Carlo simulation; Randomness parameter; Copolymer heterogeneity; Azeotrope point
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A Monte Carlo method was used to take thorough account of the influences of different reactivity ratios and initial feed compositions on copolymer microstructure. The model proves the lack of azeotropic behavior in systems in which r(A) > 1 and r(B) < 1 or vice versa; it is also able to calculate the drift in the copolymer properties: copolymer composition, and randomness parameter. Moreover, for each reactivity ratio pair given, there is a unique reaction conversion, at which macromolecules produced inherit their maximum allowed alterations. This critical conversion declines as initial feed composition increases. However, for systems with r(A) > 1 and r(B) > 1, as well as those with r(A) < 1 and r(B) < 1, the azeotropic behavior of the reactions is clearly observed. Besides, copolymer composition reaches azeotrope point at the end of the reaction when r(A) > 1 and r(B) > 1. Finally, for systems in which r(A) > 1 and r(B) > 1, randomness parameter becomes maximum at azeotrope point when r(A) equals r(B).
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