Journal
CHINESE JOURNAL OF ORGANIC CHEMISTRY
Volume 38, Issue 8, Pages 1949-1962Publisher
SCIENCE PRESS
DOI: 10.6023/cjoc201803013
Keywords
transition-metal-catalysis; ammonium salt; cross-coupling reaction; C-N bond cleavage
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Funding
- National Natural Science Foundation of China [21702212, 21772208, 21602230]
- Natural Science Foundation of Jiangsu Province [BK20161260]
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Amines containing carbon-nitrogen (C-N) bonds are widely distributed in natural products, drug molecules and functional materials. C-N bonds are one of the most abundant and inert bonds in organic molecules. Selective cleavage of C-N bonds to construct carbon-carbon (C-C) and carbon-heteroatom (C-X) bonds represents a new synthetic method in organic synthesis. It is difficult for the direct cleavage of C-N bond. Ammonium salts are a series of stable compounds easily obtained from amines. The recent progress of transition-metal-catalyzed cross-coupling reactions via C-N bond cleavage using ammonium salts as starting materials is summerized.
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