Journal
CHINESE JOURNAL OF ORGANIC CHEMISTRY
Volume 38, Issue 8, Pages 1885-1896Publisher
SCIENCE PRESS
DOI: 10.6023/cjoc201804031
Keywords
alkaline-earth-metals catalyst; hydrofunctionalization reaction; mechanism study; recent advance
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Funding
- Basic and Frontier Research Project of Chongqing Science and Technology Commission [cstc2017jcyjAX0371]
- Project of Science and Technology Collaborative Innovation Platform Construction of Chongqing University of Education [2017XJPT01]
- University-level Key Projects of Chongqing University of Education [KY201704A]
- Scientific Research Foundation of Chongqing University of Education [2017BSRC001]
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Alkaline-earth-metal compounds have been widely concerned due to its abundant reserve and the low-cost. In recent years, alkaline-earth-metal catalysis has achieved great progress in dehydrocoupling, hydroboration, hydrophosphination, hydroamination, hydrosilylation reactions experimentally and therotically. These types of reaction and catalytic mechanism, leading to indentify the role of alkaline-earth-metal in hydrogenation and dehydrogenation reaction are summarized. These reactions, in which the metal-hydride act as active species, generally undergo the reaction pathway involving the cleavage and formation of the metal-hydride covalent bond. The reaction features and mechanisms are generally recognized accrossing to the classification and discussion of these reactions, which would provide guidance for further development of alkaline-earth-metal catalysis.
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