Journal
CHINESE JOURNAL OF ORGANIC CHEMISTRY
Volume 33, Issue 5, Pages 1096-1099Publisher
SCIENCE PRESS
DOI: 10.6023/cjoc2012012049
Keywords
selenium; catalysis; green chemistry; cyclohexane-1,2-diol; oxidation
Categories
Funding
- National Natural Science Fundation of China [21202141]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Opening Foundation of the Key Laboratory of Environmental Materials and Engineering of Jiangsu Province [K11024, K090030]
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The diphenyldiselenide catalyzed oxidation of cyclohexene by hydrogen peroxide led to cyclohexane-1,2-diol with high conversion and selectivity. Compared with traditional metal catalyst, selenium catalysts are cheaper and less harmful to environment. This synthetic method is also clean and highly atom-economic. Therefore, this reaction is highly applicable.
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