4.5 Article

Synthesis of Macrocyclic Oligoparaphenylenes Derived from Anthracene Photodimer

Journal

CHINESE JOURNAL OF CHEMISTRY
Volume 36, Issue 12, Pages 1135-1138

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201800341

Keywords

oligoparaphenylene; macrocycles; anthracene photodimer; cycloaddition; cycloreversion; photochemistry

Funding

  1. National Natural Science Foundation of China [21672227]
  2. Strategic Priority Research Program of Chinese Academy of Sciences [XDB17000000]
  3. National Key Research and Development Program of China [2017YFA0206903]
  4. Recruitment Program of Global Experts, CAS Key Laboratory of Photochemical Conversion and Optoelectronic Materials
  5. TIPC Director's Fund

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Two oligoparaphenylene-derived macrocycles were prepared using the anthracene photodimerization-cycloreversion strategy. The computational and experimental properties of these cyclic oligoparaphenylenes were conducted and compared with that of [12]cycloparaphenylene.

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