4.5 Article

Efficient C-S Cross-Coupling of Thiols with Aryl Iodides Catalyzed by Cu(OAc)2• H2O and 2,2'- Biimidazole

Journal

CHINESE JOURNAL OF CHEMISTRY
Volume 32, Issue 3, Pages 212-218

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201300830

Keywords

CS cross coupling reaction; Cu(OAc)(2)center dot H2O; 2; 2-biimidazole; aryl sulfides

Funding

  1. Soochow University

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The classical Ullmann CS cross coupling reaction of aryl iodides with aromatic/alkyl thiols under catalysis of 15 mol% Cu(OAc)(2)H2O and 15 mol% 2,2-biimidazole works at 80 degrees C in DMSO for 3 h to provide a variety of aryl sulfides in good to excellent yields.

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