Journal
CHINESE JOURNAL OF CHEMISTRY
Volume 32, Issue 2, Pages 117-122Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201300541
Keywords
alcohol; aldehyde; photooxidation; TEMPO; molecular oxygen
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Funding
- National Natural Science Foundation of China [21102097]
- Specialized Research Fund for the Doctoral Program of Higher Education [20103201120006]
- Beijing National Laboratory for Molecular Sciences (BNLMS)
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A homogeneous visible light photoredox TEMPO-mediated selective oxidation of primary alcohols to the corresponding carbonyl compounds was developed using molecular oxygen from air as the terminal oxidant. Ru(bpy)(3)(PF6)(2) (bpy: bipyridyl) and Ir(dtb-bpy)(ppy)(2)(PF6) (dtb-bpy: 4,4-di-tert-butyl-2,2-bipyridyl; ppy: 2-phenylpyridine) were used as the sensitizers.
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