4.5 Article

Copper- and Silver-Mediated Cyanation of Aryl Iodides Using DDQ as Cyanide Source

Journal

CHINESE JOURNAL OF CHEMISTRY
Volume 31, Issue 4, Pages 449-452

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201201140

Keywords

copper; silver; cyanation; aryl iodides; DDQ

Funding

  1. National Natural Science Foundation of China [21272178]
  2. Natural Science Foundation of Zhejiang Province [R4110294, LY12B02010]

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A new copper and silver-mediated cyanation of aryl iodides with DDQ as a cyanide source is achieved, providing nitriles with good yields. This new approach represents a safe method leading to aryl nitriles.

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