Journal
CHINESE JOURNAL OF CHEMISTRY
Volume 31, Issue 7, Pages 885-891Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201300411
Keywords
difluoromethylenation; heteroarenes; visible-light photocatalysis
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Funding
- National Natural Science Foundation of China [21072028, 21272036]
- National Basic Research Program of China [2012CB21600]
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A mild and versatile approach for the direct introduction of ethoxycarbonyldifluoromethyl-group to heteroarenes via visible-light photocatalysis has been developed. The new photoredox protocol has enabled the difluoromethylenation of heteroarenes containing a wide range of common functional groups under mild conditions.
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