Journal
CHINESE JOURNAL OF CHEMISTRY
Volume 31, Issue 1, Pages 37-39Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201200994
Keywords
ss-keto acids; isochromans; 2,2,6-6-tetramethylpiperdine-1-oxoammonium salts; decarboxylation; alkylation
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Funding
- National Natural Science Foundation of China [21232007, 21172206]
- National Basic Research Program of China (973 Program) [2010CB833300]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1189]
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An unprecedented decarboxylative alkylation reaction of beta-keto acids with isochromans has been developed under oxidative conditions. A range of beta-keto acids smoothly undergo decarboxylative alkylation with isochromans in the presence of 2,2,6,6-tetramethylpiperdine-1-oxoammonium hexafluorophosphate to give structurally diverse 1-acylmethylisochromans in moderate to excellent yields with extremely high regioselectivity.
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