Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 45, Pages 13293-13296Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201506918
Keywords
fluorescence; homogeneous catalysis; hydrogen; iridium; N-heterocyclic carbene
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Funding
- DFG [Pl 178/18-1]
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A Crabtree-type Ir-I complex tagged with a fluorescent dye (bodipy) was synthesized. The oxidative addition of H-2 converts the weakly fluorescent Ir-I complex (phi=0.038) into a highly fluorescent Ir-III species (phi=0.51). This fluorogenic reaction can be utilized for the detection of H-2 and to probe the oxidative addition step in the catalytic hydrogenation of olefins.
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