4.5 Article

Preparation of Chiral 4,4′-Biphenylene-silica Nanoribbons

Journal

CHINESE JOURNAL OF CHEMISTRY
Volume 27, Issue 10, Pages 1860-1862

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.200990311

Keywords

silica; nanoribbon; sol-gel; self-assemble

Funding

  1. National Natural Science Foundation of China [20871087]
  2. Natural Science Foundation of Jiangsu Province [BK2007047]
  3. Program for New Century Excellent Talents in University
  4. Program of Innovative Research Team of Soochow University

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A sol-gel transcription process was carried out using an anionic gelator 12K and TMAPS as the co-structure-directing agent, as well as 4,4'-bis(triethoxysilyl)biphenyl as a hybrid silica source. It is interesting to find that the chirality of the organic self-assemblies of 12K was successfully transferred to the 4,4'-biphenylene-silica nanoribbons which are potentially applied in chiral catalysis

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