Journal
CHINESE JOURNAL OF CHEMISTRY
Volume 27, Issue 4, Pages 623-627Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.200990101
Keywords
double carbonylation; carbon monoxide; alpha-keto amide
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Funding
- National Natural Science Foundation of China [20533080, 20625308]
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The double carbonylation of iodobenzene and diethylamine proceeds smoothly in the presence of Pd/C and carbon monoxide to afford the corresponding alpha-keto amide in good yields with excellent selectivity. In addition, other aryl iodides and secondary amines also react under similar conditions to form alpha-keto amides in good yields.
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