Journal
CHINESE JOURNAL OF CHEMICAL PHYSICS
Volume 24, Issue 3, Pages 365-372Publisher
CHINESE PHYSICAL SOC
DOI: 10.1088/1674-0068/24/03/365-372
Keywords
Triblock copolymer; Mesostructural stability; Self-assembly; Ordered mesoporous carbon
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Funding
- National Natural Science Foundation of China [20872135]
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Various ordered mesoporous carbons (OMCs) have been prepared by evaporation-induced triconstituent co-assembly method. Their mesostructural stability under different carbon content, aging time and acidity were conveniently monitored by X-ray diffraction, transmission electron microscopy, and N(2) sorption isotherms techniques. The results show mesostructural stability of OMCs is enhanced as the carbon content increases from 36% to 46%, further increasing carbon content deteriorates the mesostructural stability. Increasing aging time from 0.5 h to 5.0 h make the mesostructural stability go through an optimum (2.0 h) and gradually reduce framework shrinkage of the OMCs. Highly OMCs can only be obtained in the acidity range of 0.2-1.2 mol/L HCl, when the acidity is near the isoelectric point of silica, the resulting OMCs have the best mesostructure stability. Under the optimum condition, the carbon content of 46%, aging time of 2.0 h, and 0.2 mol/L HCl, the resulting OMCs have the best mesostructure stability and the highest BET surface areas of 2281 m(2)/g.
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