Journal
CHINESE JOURNAL OF CHEMICAL ENGINEERING
Volume 17, Issue 3, Pages 407-411Publisher
CHEMICAL INDUSTRY PRESS CO LTD
DOI: 10.1016/S1004-9541(08)60224-4
Keywords
ionic liquid; cyclohexane oxidation; ZSM-5; catalysis
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Heterogeneous oxidation of cyclohexane by tent-butyl hydroperoxide (TBHP) was carried out over ZSM-5 catalysts with different Si/Al ratios in ionic liquids and organic molecular solvents. Higher yield and selectivity of the desired products were found in ionic liquids than in molecular solvents. The conversion of cyclohexane exhibits a decrease from 15.8% to 10.8% with the increase of Si/Al ratio of the HZSM-5 catalyst, and all the catalysts exhibit good selectivity of monofunctional oxidation products at around 97%. The activity of catalyst is found strongly dependent on the alkyl chain length of ionic liquid.
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