Journal
CHINESE CHEMICAL LETTERS
Volume 24, Issue 7, Pages 593-596Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2013.03.040
Keywords
Layered double hydroxides; Ternary copper complexes; Intercalation; Characterization; Stability in solution
Categories
Funding
- Beijing Municipal Natural Science Foundation [2112022]
- Key Laboratory of Radiopharmaceuticals of Ministry of Education (College of Chemistry, Beijing Normal University)
- Analytical and Testing Center of Beijing Normal University
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Four Cu2+ complexes of salicylidene-amino acid Schiff base with 1,10-phenanthroline (Phen) or 2,2'-bipyridine (Bipy) were successfully intercalated in interlayer galleries of Mg/Al-NO3-layered double hydroxide (LDH) by the swelling-restored method. The hybrids were characterized by elemental analysis, X-ray diffraction, FT-IR spectra, UV-vis DRS, TG-DTA and SEM observation. Good protection of the complexes by LDH in neutral and weak acidic solutions was revealed by UV spectra, cyclic voltammograms and luminescence spectra. (C) 2013 Ming-Zhao Wang. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
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