Journal
CHINESE CHEMICAL LETTERS
Volume 24, Issue 1, Pages 45-48Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2012.12.013
Keywords
Benzyl halides; Bromination; Hypervalent; Iodination
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Funding
- Scientific Research Fundings of the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry
- China-France Le Programme Xu Guangqi [27967RE]
- Chongqing University [CDJRC10220004, CDJZR11220005]
- Natural Science Foundation Project of CQ CSTC [2010BB5064]
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An effective approach for the direct benzylhalogenation with in situ generation of hypervalent halides has been developed. A variety of benzyl halides are produced in moderate to excellent yields (up to 99%) with high regioselectivities. UV absorption spectrum is employed to detect the formation of tert-butyl hypoiodite. (C) 2012 Yan Xiong. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
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