Journal
CHINESE CHEMICAL LETTERS
Volume 23, Issue 1, Pages 69-72Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2011.10.009
Keywords
Lithium naphthalenide; Reduction; Diphenylacetylene; Diene derivatives
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Funding
- National Science Foundation of China [50673094, 20774102]
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The reduction of diphenylacetylene with lithium naphthalenide produced two kinds of intermediates, 1 or 2, depending on the ratio of diphenylacetylene to lithium naphthalenide. A series of polyaryl substituted ethylene/diene derivatives were synthesized by reaction of electrophiles with the corresponding intermediates produced in situ. All new compounds were fully characterized, and their single crystal structures were determined. (C) 2011 Shu Hong Li. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
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