Journal
CHINESE CHEMICAL LETTERS
Volume 23, Issue 11, Pages 1311-1314Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2012.09.019
Keywords
2,6-Pyridinediamine; Electrochemical polymerization; Cyclic voltammetry; SEM; FT-IR
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Funding
- National Natural Science Foundation of China [21275023]
- Natural Science Foundation of Jiangsu Province [BK2012593]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
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Electrochemical synthesis of poly(2,6-pyridinediamine) (PPa) in aqueous sodium hydroxide solution has been carried out by using cyclic voltammetry for the first time. The scanning electron microscopy (SEM) revealed the interpenetrating network structure of the as-prepared PPa film, which makes it possible that anions can be doped into the polymer in the oxidation process, and vice versa in the reduction process. The results from FT-IR spectrum provided a possible polymerization mechanism of 2,6-pyridinediamine. (C) 2012 Yong Kong. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
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