4.7 Article

Off-on-off luminescent switching of a dye containing imidazo[4, 5-f][1,10]phenanthroline

Journal

CHINESE CHEMICAL LETTERS
Volume 22, Issue 6, Pages 647-650

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2010.12.005

Keywords

Fluorescence switch; Imidazo[4,5-f][1,10]phenanthroline; Triphenylamine; Intramolecular charge transfer (ICT)

Funding

  1. State National Natural Science Foundation of China [50325311]
  2. National 863 Project Foundation of China [2007AA10Z334]

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A new acid base fluorescent switch containing both imidazo[4,541[1,10]-phenanthroline and triphenylamine groups has been synthesized. Its fluorescence emissions and absorptions can be reversibly changed through protonation/deprotonation of imidazole and amine moiety by controlling the intramolecular charge transfer (ICT) process, leading to off on off fluorescent molecular switching. (C) 2010 Hai Guang Zhang. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

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