Journal
CHIMIA
Volume 63, Issue 11, Pages 709-713Publisher
SWISS CHEMICAL SOC
DOI: 10.2533/chimia.2009.709
Keywords
Electron transfer; Hydrogen; Ir(III) Photosensitizers; Photocatalysis; Water splitting
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The sun is a plentiful source of clean, renewable power, and the direct conversion of solar to chemical energy is a desirable goal. The collective efforts of the Bernhard group to develop molecular catalytic systems for visible-light water splitting are reviewed. Combinatorial synthesis and high-throughput screening techniques enabled the development of a series of photosensitizers; with a wide range of photophysical and electrochemical properties. Parallel evaluation of the iridium(III) photosensitizers; in photocatalytic water reduction systems utilizing cobalt-, platinum-, or rhodium-based water reduction catalysts resulted in systems that exhibited more than 5000 turnovers with quantum yields of 34% and turnover frequencies of 500 hr(-1). For the complementary water oxidation system, the catalysts based on cyclometallated iridium complexes are robust and tunable, which allows for the rapid study of water oxidation reactions through targeted ligand modification.
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