4.8 Article

LiCl as Phase-Transfer Catalysts to Synthesize Thin Co2P Nanosheets for Oxygen Evolution Reaction

Journal

CHEMSUSCHEM
Volume 12, Issue 9, Pages 1911-1915

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201801691

Keywords

cobalt phosphide; lithium chloride; nanosheets; oxygen evolution reaction; phase transfer

Funding

  1. National Key Technologies R & D Program of China [2018YFA0209301]
  2. National Natural Science Foundation of China [21425309, 21761132002, 21861130353]
  3. China Postdoctoral Science Foundation [2017M622051]
  4. 111 Project [D16008]

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Inorganic salts have been widely studied as templates for the synthesis of 2D layer structures. However, these salts normally can only serve as templates without any catalytic activity. Here, we report that LiCl used for the synthesis of ultrathin nanosheets not only serves as template for the synthesis of ultrathin Co2P nanosheets with a thickness of 0.7nm but also acts as a catalyst that induces the phase-transfer from CoP to Co2P. The Co2P nanosheets have a high electrochemical performance for oxygen evolution reaction.

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