Journal
CHEMSUSCHEM
Volume 11, Issue 20, Pages 3586-3590Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201801180
Keywords
amines; C-C coupling; dehydrogenation; gold; heterogeneous catalysis
Funding
- National Natural Science Foundation of China [21402124, 21777106]
- Training Foundation for Outstanding Young Teachers in Higher Education Institutions of Guangdong [YQ2015145]
- Project of Featured Innovation in Higher Education Institutions of Guangdong [2017KTSCX159]
- Shenzhen Science and Technology Foundation [JCYJ2017030214365 8923]
- Natural Science Foundation of SZU [827000 038]
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Polydimethylsiloxane (PDMS, a stable hydrophobic polymer material) sponge-supported nanometer-sized gold can be used as a highly efficient recyclable catalyst for cross-dehydrogenative coupling of tertiary amines with various nucleophiles in water. This PDMS sponge nanometer gold catalyst can provide much better activity than the free nanometer gold in water. The reaction can be scaled up by using an easy-to-build continuous flow reactor. These results indicate the potential application of porous hydrophobic PDMS sponge material as a promising support for highly efficient recyclable catalysts in water.
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