Journal
CHEMSUSCHEM
Volume 7, Issue 7, Pages 1858-1863Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201400157
Keywords
carbon; electrochemistry; electrospinning; lithium; nanostructures
Funding
- National Research Foundation (NRF
- Singapore) [NRF-CRP4-2008-03]
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This is the first report of the utilization of TiNb2O7 as an insertion-type anode in a lithium-ion hybrid electrochemical capacitor (Li-HEC) along with an activated carbon (AC) counter electrode derived from a coconut shell. A simple and scalable electrospinning technique is adopted to prepare one-dimensional TiNb2O7 nanofibers that can be characterized by XRD with Rietveld refinement, SEM, and TEM. The lithium insertion properties of such electrospun TiNb2O7 are evaluated in the half-cell configuration (Li/TiNb2O7) and it is found that the reversible intercalation of lithium (approximate to 3.45 mol) is feasible with good capacity retention characteristics. The Li-HEC is constructed with an optimized mass loading based on the electrochemical performance of both the TiNb2O7 anode and AC counter electrode in nonaqueous media. The Li-HEC delivers very high energy and power densities of approximately 43 Whkg(-1) and 3 kWkg(-1), respectively. Furthermore, the AC/TiNb2O7 Li-HEC delivers a good cyclability of 3000 cycles with about 84% of the initial value.
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