Journal
CHEMSUSCHEM
Volume 7, Issue 11, Pages 3157-3163Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201402584
Keywords
diester; hydroesterification; isosorbide; olefin; palladium
Funding
- ANR [2010-006-01]
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The hydroesterification of alpha olefins has been used to synthesize diesters from bio-based secondary diols: isosorbide, isomannide, and isoidide. The reaction was promoted by 0.2% palladium catalyst generated insitu from palladium acetate/triphenylphosphine/para-toluene sulfonic acid. Optimized reaction conditions allowed the selective synthesis of the diesters with high yields and the reaction conditions could be scaled up to the synthesis of hundred grams of diesters from isosorbide and 1-octene with solvent-free conditions.
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