Journal
CHEMSUSCHEM
Volume 8, Issue 1, Pages 177-183Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201402520
Keywords
hierarchical superstructures; prussian blue; prussian blue analogues; pseudocapacitive materials; spontaneous assembly
Funding
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences
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Hierarchically superstructured Prussian blue analogues (hexacyanoferrate, M= Ni-II, Co-II and Cu-II) are synthesized through a spontaneous assembly technique. In sharp contrast to macroporous-only Prussian blue analogues, the hierarchically superstructured porous Prussian blue materials are demonstrated to possess a high capacitance, which is similar to those of the conventional hybrid graphene/MnO2 nanostructured textiles. Because sodium or potassium ions are involved in energy storage processes, more environmentally neutral electrolytes can be utilized, making the superstructured porous Prussian blue analogues a great contender for applications as high-performance pseudocapacitors.
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