Journal
CHEMSUSCHEM
Volume 7, Issue 3, Pages 738-742Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201301128
Keywords
benzene; carbon nitride; ferrocene; phenol; photocatalysis
Funding
- National Basic Research Program of China [2013CB632405]
- National Natural Science Foundation of China [21033003, 21173043]
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Ferrocene moieties were heterogenized onto carbon nitride polymers by a covalent CN linkage bridging the two conjugation systems, enabling the merging of the redox function of ferrocene with carbon nitride photocatalysis to construct a heterogeneous Photo-Fenton system for green organocatalysis at neutral conditions. The synergistic donor-acceptor interaction between the carbon nitride matrix and ferrocene group, improved exciton splitting, and coupled photocatalytic performance allowed the direct synthesis of phenol from benzene in the presence of H2O2 under visible light irradiation. This innovative modification method will offer an avenue to construct functionalized two-dimensional polymers useful also for other green synthesis processes using solar irradiation.
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