Journal
CHEMSUSCHEM
Volume 7, Issue 1, Pages 96-100Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201300832
Keywords
1,6-hexanediol; formic acid; heterogeneous catalysis; renewable resources; transfer hydrogenation
Funding
- Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan [25420825, 25820392]
- Grants-in-Aid for Scientific Research [25420825] Funding Source: KAKEN
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A new approach is developed for hydrogenolytic ring opening of biobased 5-hydroxymethylfurfural (HMF), dehydration product of hexoses, towards 1,6-hexanediol (HDO) under atmospheric pressure. The highest yield of HDO, 43%, is achieved over reusable Pd/zirconium phosphate (ZrP) catalyst at 413 K in the presence of formic acid as hydrogen source. In comparison with various Bronsted and/or Lewis acidic supports, the specific Bronsted acidity on ZrP support effectively accelerated the cleavage of C-O bond in a furan ring.
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