Journal
CHEMSUSCHEM
Volume 6, Issue 5, Pages 865-871Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201300032
Keywords
CC coupling; green chemistry; heterogeneous catalysis; metalorganic frameworks; zeolites
Funding
- European Community [228862]
- Czech Grant Agency (Centre of Excellence) [P106/12/G015]
- KRICT
- NRF/KICOS [KK-1201-F0]
- International Collaboration Programme [KN-1127]
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The catalytic performance of a set of metalorganic frameworks [CuBTC, FeBTC, MIL-100(Fe), MIL-100(Cr), ZIF-8, MIL-53(Al)] was investigated in the Prins condensation of -pinene with formaldehyde and compared with the catalytic behavior of conventional aluminosilicate zeolites BEA and FAU and titanosilicate zeolite MFI (TS-1). The activity of the investigated metalorganic frameworks (MOFs) increased with the increasing concentration of accessible Lewis acid sites in the order ZIF-8
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