Journal
CHEMSUSCHEM
Volume 5, Issue 9, Pages 1767-1772Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201200113
Keywords
amines; biomass; carbohydrates; homogeneous catalysis
Funding
- Research & Development Corporation (RDC) of Newfoundland and Labrador
- DAAD RISE worldwide (internship)
- NSERC of Canada
- CFI
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An efficient process for converting N-acetyglucosamine (NAG) into 3-acetamido-5-acetylfuran (3A5AF) is reported. 3A5AF is proposed as an N-containing platform chemical, which contains renewable nitrogen. In the reported method NAG, in the presence of boric acid (B(OH)3) and sodium chloride (NaCl), produces 58?% yield 3A5AF in dimethylacetamide under microwave irradiation (220?degrees C, 15 min). A maximum yield of 62?% was obtained in the presence of 4 equivalent NaCl. Performing ICPMS analysis on NAG from different chemical suppliers highlighted the importance of Cl and B levels in this process. Trace impurities are, therefore, important considerations in biomass transformations. This solution-phase process produces approximately 30 times more 3A5AF than a pyrolysis route reported previously.
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