Journal
CHEMSUSCHEM
Volume 5, Issue 11, Pages 2249-2254Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201200320
Keywords
hydrogenation; lactones; metathesis; renewable resources; ruthenium
Funding
- ADEME
- Region Bretagne
Ask authors/readers for more resources
The modification of methyl ricinoleate by etherification of the hydroxyl group was accomplished by using a nonclassical ruthenium-catalyzed allylation reaction and also by esterification. Methyl ricinoleate derivatives were engaged in ring-closing metathesis (RCM) reactions leading to biosourced 3,6-dihydropyran and alpha,beta-unsaturated lactone derivatives with concomitant production of polymer precursors. Sequential RCM/hydrogenation and RCM/cross-metathesis were also implemented as a straightforward method for the synthesis of tetrahydropyran and lactone derivatives as well as valuable monomers (i.e., polyamide precursors).
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available