Journal
CHEMSUSCHEM
Volume 5, Issue 8, Pages 1597-1601Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201100702
Keywords
adsorption; pi interactions; metal-organic frameworks; nickel; microporous materials
Funding
- National Basic Research Program of China (973 Programs) [2011CB932504, 2012CB821705]
- NSFC [21073191]
- NSF of Fujian Province [2011J06005]
- State Key Laboratory of Heavy Oil Processing
- Innovation Program of CAS [KJCX2-YW-H21]
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Presented here is a chiral microporous metalorganic framework material with a three-fold interpenetrating diamond-type structural topology and interesting properties for selective separation. The material has a high storage capacity for CO2 gas (4.23 mmol?g-1 at 273 K and 1 bar) and shows fantastic temperature-dependent selectivity for CO2 over N2. Moreover, this multifunctional material, which has a rich p system, can selectively adsorb benzene over cyclohexane at low pressure (0.05 bar) at 298 K.
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