Journal
CHEMSUSCHEM
Volume 5, Issue 1, Pages 188-193Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201100355
Keywords
heck reaction; homogeneous catalysis; nanofiltration; palladium; recycling
Funding
- EC Marie Curie Action
- Engineering and Physical Sciences Research Council [EP/D068851/1] Funding Source: researchfish
- EPSRC [EP/D068851/1] Funding Source: UKRI
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Organic solvent nanofiltration (OSN) is a recently commercialized technology, which we have used to develop a method for the separation of a target product and the Pd catalyst from a Heck coupling postreaction mixture. The experimental setup included commercially available polyimide copolymer membranes with molecular weight cut-off (MWCO) values in the range of 150300 Da, acetone as the solvent, and a working pressure (N2) of 3 MPa. The investigation of the membranes revealed that a membrane with a MWCO of 200 Da provided quantitative retention of the Pd catalyst and quantitative recovery of the target product by means of a cross-flow dia-nanofiltration procedure.
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