4.8 Review

Oriented Nanostructures for Energy Conversion and Storage

Journal

CHEMSUSCHEM
Volume 1, Issue 8-9, Pages 676-697

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.200800087

Keywords

energy conversion; energy storage; materials science; nanostructures

Funding

  1. Pacific Northwest National Laboratory
  2. Office of Basic Energy Sciences
  3. U.S. Deportment of Energy (DOE)
  4. Battelle Memorial Institute for the Deportment of Energy [DE-AC05-76 L01830]
  5. University of Washington
  6. National Science Foundation [DMI-0455994, DMR-0605159]
  7. Air Force Office of Scientific Research [FA9550-06-1-032]
  8. Department of Energy [DE-FG02-07ER46467]
  9. Washington Technology Center
  10. Washington Research Foundation
  11. EnerG2, LLC

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Recently, the role of nonostructured materials in addressing the challenges in energy and natural resources has attracted wide attention. In particular, oriented nonostructures demonstrate promising properties for energy harvesting, conversion, and storage. In this Review, we highlight the synthesis and application of oriented nanostructures in a few key areas of energy technologies, namely photovoltaics, batteries, supercapacitors, and thermoelectrics. Although the applications differ from field to field, a common fundamental challenge is to improve the generation and transport of electrons and ions. We highlight the role of high surface area to maximize the surface activity and discuss the importance of optimum dimension and architecture, controlled pore channels, and alignment of the nonocrystalline phase to optimize the transport of electrons and ions. Finally, we discuss the challenges in attaining integrated architectures to achieve the desired performance. Brief background information is provided for the relevant technologies, but the emphasis is focused mainly on the nanoscale effects of mostly inorganic-based materials and devices.

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