4.5 Article

Straightforward Oxidation of a Copper Substrate Produces an Underwater Superoleophobic Mesh for Oil/Water Separation

Journal

CHEMPHYSCHEM
Volume 14, Issue 15, Pages 3489-3494

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201300691

Keywords

copper; oil/water separation; oxidation; superhydrophilic; underwater superoleophobic

Funding

  1. National Natural Science Foundation [51173099]
  2. National High Technology Research and Development Program of China [2012AA030306]
  3. National Research Fund for Fundamental Key Projects [2011CB935700]

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A superhydrophilic and underwater superoleophobic Cu(OH)(2)-covered mesh with micro- and nanoscale hierarchical composite structures is successfully fabricated through a one-step chemical oxidation of a smooth-copper mesh. Such mesh, without any further modification, can selectively separate water from oil/water mixtures with high separation efficiency, and possess excellent stability even after 60 uses. This method provides a simple, low-cost, and scalable strategy for the purification of oily wastewater.

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