Journal
CHEMPHYSCHEM
Volume 14, Issue 16, Pages 3655-3666Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201300529
Keywords
chemical imaging; heterogeneous catalysis; mesoscale science; operando spectroscopy; X-ray microscopy
Funding
- Utrecht University
- Dutch National Research School Combination Catalysis Controlled by Chemical Design (NRSC-C)
- Netherlands Organisation for Scientific Research (NWO)
- Dow Chemical and Shell
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Heterogeneous catalysts often consist of an active metal (oxide) in close contact with a support material and various promoter elements. Although macroscopic properties, such as activity, selectivity and stability, can be assessed with catalyst performance testing, the development of relevant, preferably quantitative structure-performance relationships require the use of advanced characterisation methods. Spectroscopic imaging in the hard X-ray region with nanometer-scale resolution has very recently emerged as a powerful approach to elucidate the hierarchical structure and related chemistry of catalytic solids in action under realistic reaction conditions. This X-ray-based chemical imaging method benefits from the combination of high resolution (approximate to 30 nm) with large X-ray penetration and depth of focus, and the possibility for probing large areas with mosaic imaging. These capabilities make it possible to obtain spatial and temporal information on chemical changes in catalytic solids as well as a wide variety of other functional materials, such as fuel cells and batteries, in their full complexity and integrity. In this concept article we provide details on the method and setup of full-field hard X-ray spectroscopic imaging, illustrate its potential for spatiotemporal chemical imaging by making use of recent showcases, outline the pros and cons of this experimental approach and discuss some future directions for hierarchical functional materials research.
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